List of Tables

Chapter 3
Table 1. Results from the hydrosilylation of olefins	81
Appendix A
Table 1. Observed pseudo-first order rate constants for disappearance of 5 at different phenylsilane concentrations.	127
Table 2. Observed pseudo-first order rate constants for disappearance of 5 at different concentrations of (CH2)3SiH2.	127
Table 3. First order rate constants for decomposition of 9 and 9-d3, at different starting concentrations, using initial rates.	128
Table 4. First order rate constants for decomposition of 9, at five different temperatures.	128
Table 5. Crystallographic data for compounds 4, 6.1/2Et2O, and 7.	129
Table 5 (cont). Crystallographic data for compounds 9 and 12.	131
Table 6. Atomic coordinates and Biso/Beq for Cp*Ta[=N(C6H3Me)2NSiMe3]Cl (4).	133
Table 7. Anisotropic Displacement Parameters for Cp*Ta[=N(C6H3Me)2NSiMe3]Cl (4).	134
Table 8. Bond Lengths (Å) for Cp*Ta[=N(C6H3Me)2NSiMe3]Cl (4).	135
Table 9. Bond Angles (o) for Cp*Ta[=N(C6H3Me)2NSiMe3]Cl (4).	135
Table 10. Least Squares Planes for Cp*Ta[=N(C6H3Me)2NSiMe3]Cl (4).	136
Table 11. Atomic coordinates and Biso/Beq for Cp*Ta[=N(C6H3Me)2NSiMe3]- [h2-(2,6-Me2C6H3)N=CMe].1/2Et2O (6.1/2Et2O).	137
Table 12. Anisotropic Displacement Parameters for Cp*Ta[=N-(C6H3Me)2NSiMe3]- [h2-(2,6-Me2C6H3)N=CMe].1/2Et2O (6.1/2Et2O).	138
Table 13. Bond Lengths (Å) for Cp*Ta[=N-(C6H3Me)2NSiMe3]- [h2-(2,6-Me2C6H3)N=CMe].1/2Et2O (6.1/2Et2O)	139
Table 14. Bond Angles (o) for Cp*Ta[=N(C6H3Me)2NSiMe3]- [h2-(2,6-Me2C6H3)N=CMe].1/2Et2O (6.1/2Et2O).	140
Table 15. Least Squares Planes for Cp*Ta[=N-(C6H3Me)2NSiMe3]- [h2-(2,6-Me2C6H3)N=CMe].1/2Et2O (6.1/2Et2O).	141
Table 16. Atomic coordinates and Biso/Beq for {Cp*Ta[MeN(C6H3Me)2NSiMe3]Me}+I- (7).	142
Table 17. Anisotropic Displacement Parameters for {Cp*Ta[MeN(C6H3Me)2SiMe3]Me}+I- (7).	143
Table 18. Bond Lengths (Å) for {Cp*Ta[MeN(C6H3Me)2NSiMe3]Me}+I- (7).	144
Table 19. Bond Angles (o) for {Cp*Ta[MeN(C6H3Me)2NSiMe3]Me}+I- (7).	145
Table 20. Least Squares Planes for {Cp*Ta[MeN(C6H3Me)2NSiMe3]Me}+I- (7).	146
Table 21. Atomic coordinates and Biso/Beq for Cp*Ta[PhSiH2N(C6H3Me)2NSiMe3](H)Me (9).	146
Table 22. Anisotropic Displacement Parameters for Cp*Ta[PhSiH2N(C6H3Me)2NSiMe3](H)Me (9).	148
Table 23. Bond Lengths (Å) for Cp*Ta[PhSiH2N(C6H3Me)2NSiMe3](H)Me (9).	149
Table 24. Bond Angles (o) for Cp*Ta[PhSiH2N(C6H3Me)2NSiMe3](H)Me (9).	149
Table 25. Least Squares Planes for Cp*Ta[PhSiH2N(C6H3Me)2NSiMe3](H)Me (9).	150
Table 26. Atomic coordinates and Biso/Beq for Cp*Ta[PhSiH2N(C6H3Me)2NSiPhHCl](H)Cl (12).	151
Table 27. Anisotropic Displacement Parameters for Cp*Ta[PhSiH2N(C6H3Me)2NSiPhHCl](H)Cl (12).	153
Table 28. Bond Lengths (Å) for Cp*Ta[PhSiH2N(C6H3Me)2NSiPhHCl](H)Cl (12).	154
Table 29. Bond Angles (o) for Cp*Ta[PhSiH2N(C6H3Me)2NSiPhHCl](H)Cl (12).	154
Table 30. Least Squares Planes for Cp*Ta[PhSiH2N(C6H3Me)2NSiPhHCl](H)Cl (12).	155
Appendix B
Table 1. Crystallographic data for compounds 2, 4, 6, and 9.	158
Table 2. Atomic coordinates and Biso/Beq for [DADMB]YCl(THF)2 (2).	160
Table 3. Anisotropic Displacement Parameters for [DADMB]YCl(THF)2 (2).	161
Table 4. Bond Lengths (Å) for [DADMB]YCl(THF)2 (2).	162
Table 5. Bond Angles (o) for [DADMB]YCl(THF)2 (2).	163
Table 6. Atomic coordinates and Biso/Beq for [DADMB]Y(OSiMe3)(THF)2 (4).	164
Table 7. Anisotropic Displacement Parameters for [DADMB]Y(OSiMe3)(THF)2 (4).	166
Table 8. Bond Lengths (Å) for [DADMB]Y(OSiMe3)(THF)2 (4).	167
Table 9. Bond Angles (o) for [DADMB]Y(OSiMe3)(THF)2 (4).	168
Table 10. Atomic coordinates and Biso/Beq for {[DADMB]YH(THF)}2.C6H6 (6).	169
Table 11. Anisotropic Displacement Parameters for {[DADMB]YH(THF)}2.C6H6 (6).	171
Table 12. Bond Lengths (Å) for {[DADMB]YH(THF)}2.C6H6 (6).	172
Table 13. Bond Angles (o) for {[DADMB]YH(THF)}2.C6H6 (6).	172
Table 14. Atomic coordinates and Biso/Beq for [DADMB]Y(NC5H6)(NC5H5)2.C5H12 (9).	173
Table 15. Anisotropic Displacement Parameters for [DADMB]Y(NC5H6)(NC5H5)2.C5H12 (9).	175
Table 16. Bond Lengths (Å) for [DADMB]Y(NC5H6)(NC5H5)2.C5H12 (9).	177
Table 17. Bond Angles (o) for [DADMB]Y(NC5H6)(NC5H5)2.C5H12 (9).	177
Appendix C
Table 1. Observed pseudo-first order rate constants for consumption of 1 at different PhMeSiH2 concentration.	181
Table 2. Observed pseudo-first order rate constants for consumption of 1 at different PhMeSiD2 concentration.	181
Table 3. Observed pseudo-first order rate constants for consumption of PhMeSiH2 at different initial concentrations of 1-hexene, PhMeSiH2, and 1 (in benzene-d6).	182
Table 4. Observed pseudo-first order rate constants for consumption of PhMeSiH2 at different initial concentrations of 1 (in THF-d8).	182
Appendix D
Table 1. Crystallographic data for compounds 3 and 7.	184
Table 2. Atomic coordinates and Biso/Beq for {[DADMB]ZrCl2}2 (3).	186
Table 3. Anisotropic Displacement Parameters for {[DADMB]ZrCl2}2 (3).	187
Table 4. Bond Lengths (Å) for {[DADMB]ZrCl2}2 (3).	188
Table 5. Bond Angles (o) for {[DADMB]ZrCl2}2 (3).	188
Table 6. Atomic coordinates and Biso/Beq for [DMBN]Zr(CH2Ph)[h6-PhCH2B(C6F5)3].3.5C6H6 (7).	189
Table 7. Anisotropic Displacement Parameters for [DMBN]Zr(CH2Ph)[h6-PhCH2B(C6F5)3].3.5C6H6 (7).	193
Table 8. Bond Lengths (Å) for [DMBN]Zr(CH2Ph)[h6-PhCH2B(C6F5)3].3.5C6H6 (7).	195
Table 9. Bond Angles (o) for [DMBN]Zr(CH2Ph)[h6-PhCH2B(C6F5)3].3.5C6H6 (7).	196
Table 10. Least Squares Planes for [DMBN]Zr(CH2Ph)[h6-PhCH2B(C6F5)3].3.5C6H6 (7).	197